Specific Photobiocatalytic Oxyfunctionalization Reactions | Zendy

Churakova Ekaterina | Zendy; Kluge Martin | Zendy; Ullrich René | Zendy; Arends Isabel | Zendy; Hofrichter Martin | Zendy; Hollmann Frank | Zendy

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Specific Photobiocatalytic Oxyfunctionalization Reactions

Author(s) -

Churakova Ekaterina,

Kluge Martin,

Ullrich René,

Arends Isabel,

Hofrichter Martin,

Hollmann Frank

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105308

Subject(s) - flavin mononucleotide , chemistry , flavin group , combinatorial chemistry , hydroxylation , stereochemistry , organic chemistry , enzyme

Turn a light on : Enantiospecific hydroxylation of nonactivated CH bonds as well as epoxidations of CC bonds are reported using a novel peroxidase from Agrocybe aegerita ( Aae APO). Aae APO represents a more active and more versatile alternative to the current gold standard, chloroperoxidase. H 2 O 2 was produced in situ by photocatalytic reduction of O 2 using simple flavin adenine mononucleotide (FMN) catalysts.

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