BaFeO 3 : A Ferromagnetic Iron Oxide | Zendy

Hayashi Naoaki | Zendy; Yamamoto Takafumi | Zendy; Kageyama Hiroshi | Zendy; Nishi Masakazu | Zendy; Watanabe Yoshitaka | Zendy; Kawakami Takateru | Zendy; Matsushita Yoshitaka | Zendy; Fujimori Atsushi | Zendy; Takano Mikio | Zendy

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BaFeO 3 : A Ferromagnetic Iron Oxide

Author(s) -

Hayashi Naoaki,

Yamamoto Takafumi,

Kageyama Hiroshi,

Nishi Masakazu,

Watanabe Yoshitaka,

Kawakami Takateru,

Matsushita Yoshitaka,

Fujimori Atsushi,

Takano Mikio

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201105276

Subject(s) - ferromagnetism , oxide , condensed matter physics , magnetic moment , moment (physics) , perovskite (structure) , materials science , ion , chemistry , crystallography , physics , metallurgy , organic chemistry , classical mechanics

Magnetic attraction : The cubic perovskite BaFeO 3 (see picture, Ba blue, Fe brown, O white), which is obtained by a low‐temperature reaction using ozone as an oxidant, exhibits ferromagnetism with a fairly large moment of 3.5 μ B per Fe ion above a small critical field of approximately 0.3 T. This specific ferromagnetism is attributed to the enhancement of O→Fe charge transfer that arises from deepening of the Fe 4+ d levels.

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