Synthesis of 1‐Phospha‐2‐boraacenaphthenes: Reductive 1,2‐Aryl Migration of 1‐Diarylboryl‐8‐dichlorophosphinonaphthalenes | Zendy

Tsurusaki Akihiro | Zendy; Sasamori Takahiro | Zendy; Wakamiya Atsushi | Zendy; Yamaguchi Shigehiro | Zendy; Nagura Kazuhiko | Zendy; Irle Stephan | Zendy; Tokitoh Norihiro | Zendy

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Synthesis of 1‐Phospha‐2‐boraacenaphthenes: Reductive 1,2‐Aryl Migration of 1‐Diarylboryl‐8‐dichlorophosphinonaphthalenes

Author(s) -

Tsurusaki Akihiro,

Sasamori Takahiro,

Wakamiya Atsushi,

Yamaguchi Shigehiro,

Nagura Kazuhiko,

Irle Stephan,

Tokitoh Norihiro

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201104971

Subject(s) - moiety , chemistry , aryl , boron , fluorescence , combinatorial chemistry , orange (colour) , stereochemistry , medicinal chemistry , organic chemistry , physics , quantum mechanics , alkyl , food science

On the move : The title compounds 1 , which are unique heterocyclic systems containing a PB bond, have been synthesized by the reduction of 1‐diarylboryl‐8‐dichlorophosphinonaphthalene derivatives (see scheme). Both experimental and theoretical results for 1 revealed an effective interaction between the phosphorus atom, boron atom, and naphthyl moiety. Furthermore, 1 exhibits orange fluorescence in solution.

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