Transition‐Metal‐Catalyzed Synthesis of Diboranes(4) | Zendy

Braunschweig Holger | Zendy; Guethlein Frank | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Transition‐Metal‐Catalyzed Synthesis of Diboranes(4)

Author(s) -

Braunschweig Holger,

Guethlein Frank

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201104854

Subject(s) - diborane , reagent , boranes , catalysis , chemistry , carbon fibers , transition metal , combinatorial chemistry , organic chemistry , computer science , boron , algorithm , composite number

The diboranes(4) bis(catecholato)diborane (B 2 Cat 2 ) and bis(pinacolato)diborane (B 2 Pin 2 ) are important precursors for organoboronic esters, which are versatile reagents for the formation of carbon–carbon bonds. A new catalytic synthesis for these compounds starts from catecholborane or pinacolborane and gives the dehydrocoupling products B 2 Cat 2 and B 2 Pin 2 with turnover numbers of up to 11 600 (see scheme).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research