Premium
Network Diversity through Decoration of Trigonal‐Prismatic Nodes: Two‐Step Crystal Engineering of Cationic Metal–Organic Materials
Author(s) -
Schoedel Alexander,
Wojtas Lukasz,
Kelley Stephen P.,
Rogers Robin D.,
Eddaoudi Mohamed,
Zaworotko Michael J.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201104688
Subject(s) - cationic polymerization , trigonal crystal system , block (permutation group theory) , planar , word (group theory) , metal , network topology , crystallography , materials science , computer science , polymer science , topology (electrical circuits) , nanotechnology , crystal structure , chemistry , combinatorics , polymer chemistry , mathematics , computer graphics (images) , geometry , computer network , metallurgy
MOMs the word! In a two‐step process, first a t rigonal‐ p rismatic P rimary M olecular B uilding B lock ([Cr 3 O(isonic) 6 ] + , tp‐PMBB‐1) was formed and then it was connected to linear linkers or square‐planar nodes to afford three novel highly charged cationic metal–organic materials (MOMs) with snx, snw , and stp topologies.