In‐Between Complex and Cluster: A 14‐Vertex Cage in [Ag 2 Se 12 ] 2+ | Zendy

Köchner Tobias | Zendy; Trapp Nils | Zendy; Engesser Tobias A. | Zendy; Lehner Anna J. | Zendy; Röhr Caroline | Zendy; Riedel Sebastian | Zendy; Knapp Carsten | Zendy; Scherer Harald | Zendy; Krossing Ingo | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

In‐Between Complex and Cluster: A 14‐Vertex Cage in [Ag 2 Se 12 ] 2+

Author(s) -

Köchner Tobias,

Trapp Nils,

Engesser Tobias A.,

Lehner Anna J.,

Röhr Caroline,

Riedel Sebastian,

Knapp Carsten,

Scherer Harald,

Krossing Ingo

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201104666

Subject(s) - dication , vertex (graph theory) , cage , selenium , chemistry , cluster (spacecraft) , crystallography , stereochemistry , molecule , combinatorics , organic chemistry , graph , computer science , mathematics , programming language

Foreshadowing a new selenium modification …? Upon treatment of red, amorphous selenium with the silver salts of two large weakly coordinating anions (WCA), the thermodynamically driven formation of [Ag 2 Se 12 ] 2+ occurred. The structure of the dication is an unprecedented D 3 d ‐symmetric 14‐vertex cage built from six six‐membered rings in a boat conformation that includes a weak argentophilic Ag–Ag bond.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research