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Softening of Pore and Interior Properties of a Metal‐Oxide‐Based Capsule: Substituting 60 Oxide by 60 Sulfide Ligands
Author(s) -
Schäffer Christian,
Todea Ana Maria,
Bögge Hartmut,
Cadot Emmanuel,
Gouzerh Pierre,
Kopilevich Sivil,
Weinstock Ira A.,
Müller Achim
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201104642
Subject(s) - oxide , softening , sulfide , metal , affinities , porosity , capsule , materials science , molecule , chemistry , mineralogy , metallurgy , composite material , geology , stereochemistry , organic chemistry , paleontology
A hard capsule gets soft : The exchange of 60 oxide by 60 sulfide ligands (see picture) in a well‐known porous metal‐oxide capsule skeleton conataining 132 metal atoms changes the interior properties as well as pore sizes, reactivities, flexibilities and affinities to guest molecules.