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Cobalt‐Catalyzed Reductive Allylation of Alkyl Halides with Allylic Acetates or Carbonates
Author(s) -
Qian Xin,
Auffrant Audrey,
Felouat Abdellah,
Gosmini Corinne
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201104390
Subject(s) - allylic rearrangement , halide , catalysis , cobalt , alkyl , chemistry , bromide , substrate (aquarium) , functional group , organic chemistry , combinatorial chemistry , oceanography , polymer , geology
An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.