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Synthesis of a Bicyclobutane Fatty Acid Identified from the Cyanobacterium Anabaena PCC 7120
Author(s) -
DeGuire Sean M.,
Ma Shutao,
Sulikowski Gary A.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201104366
Subject(s) - anabaena , cyanobacteria , chemistry , fatty acid , biology , biochemistry , bacteria , genetics
By design : A carbanion‐mediated cyclization reaction cascade serves as the key final step in the total synthesis of a novel oxylipin, which features a strained bicyclo[1.1.0]butane conjugated to a labile vinyl epoxide.
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