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The Effect of High Pressure on MOF‐5: Guest‐Induced Modification of Pore Size and Content at High Pressure
Author(s) -
Graham Alexander J.,
Allan David R.,
Muszkiewicz Anna,
Morrison Carole A.,
Moggach Stephen A.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201104285
Subject(s) - high pressure , materials science , chemical engineering , chemistry , engineering physics , engineering
Grace under pressure : In the first high‐pressure crystallographic study on the metal–organic framework MOF‐5, increasing pressure initially results in the pressure‐transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa.
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