A Trisheteroleptic Cyclometalated Ru II  Sensitizer that Enables High Power Output in a Dye‐Sensitized Solar Cell | Zendy

Bomben Paolo G. | Zendy; Gordon Terry J. | Zendy; Schott Eduardo | Zendy; Berlinguette Curtis P. | Zendy

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A Trisheteroleptic Cyclometalated Ru II Sensitizer that Enables High Power Output in a Dye‐Sensitized Solar Cell

Author(s) -

Bomben Paolo G.,

Gordon Terry J.,

Schott Eduardo,

Berlinguette Curtis P.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201104275

Subject(s) - dye sensitized solar cell , moiety , solar cell , chemistry , electrolyte , photochemistry , bipyridine , materials science , chemical engineering , stereochemistry , crystallography , electrode , optoelectronics , crystal structure , engineering

A trisheteroleptic cyclometalated ruthenium complex (see picture) bearing aliphatic substituents was synthesized, characterized, and evaluated in a dye‐sensitized solar cell (DSSC). This thiocyanate‐free dye, which has favorable structural elements to exhibit long‐term stability, generates a high power output in the DSSC with both iodide‐based and Co‐based redox shuttles.

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