Selective Catalytic Monoreduction of Phthalimides and Imidazolidine‐2,4‐diones | Zendy

Das Shoubhik | Zendy; Addis Daniele | Zendy; Knöpke Leif R. | Zendy; Bentrup Ursula | Zendy; Junge Kathrin | Zendy; Brückner Angelika | Zendy; Beller Matthias | Zendy

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Selective Catalytic Monoreduction of Phthalimides and Imidazolidine‐2,4‐diones

Author(s) -

Das Shoubhik,

Addis Daniele,

Knöpke Leif R.,

Bentrup Ursula,

Junge Kathrin,

Brückner Angelika,

Beller Matthias

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201104226

Subject(s) - phthalimides , imidazolidine , catalysis , combinatorial chemistry , chemistry , organic chemistry , phthalimide

Fluoride's new role : Selective and efficient monoreductions of imides can be achieved with polymethylhydrosiloxane (PMHS) and tetra‐ n ‐butylammonium fluoride (TBAF) as catalyst (see scheme). The system is characterized by good chemoselectivity, operational simplicity, and functional‐group tolerance; a concise mechanistic proposal was possible from in situ spectroscopic investigations.

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