Extending the Chain: Synthetic, Structural, and Reaction Chemistry of a BN Allenylidene Analogue | Zendy

Niemeyer Jochen | Zendy; Addy David A. | Zendy; Riddlestone Ian | Zendy; Kelly Michael | Zendy; Thompson Amber L. | Zendy; Vidovic Dragoslav | Zendy; Aldridge Simon | Zendy

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Extending the Chain: Synthetic, Structural, and Reaction Chemistry of a BN Allenylidene Analogue

Author(s) -

Niemeyer Jochen,

Addy David A.,

Riddlestone Ian,

Kelly Michael,

Thompson Amber L.,

Vidovic Dragoslav,

Aldridge Simon

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201103757

Subject(s) - steric effects , reactivity (psychology) , nucleophile , halide , chemistry , abstraction , boron , computational chemistry , combinatorial chemistry , medicinal chemistry , stereochemistry , organic chemistry , philosophy , epistemology , catalysis , medicine , alternative medicine , pathology

α versus γ : [CpFe(CO)(PCy 3 )(BNCMes 2 )] + , synthesized by halide abstraction, represents the first example of a BN allenylidene analogue, and features an unsaturated MBNC π system. Although DFT calculations show significant LUMO amplitude at the γ (carbon) position, primary reactivity towards nucleophiles occurs at the sterically less hindered α (boron) center.

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