Light‐Responsive Capture and Release of DNA in a Ternary Supramolecular Complex | Zendy

Nalluri Siva Krishna Mohan | Zendy; Voskuhl Jens | Zendy; Bultema Jelle B. | Zendy; Boekema Egbert J. | Zendy; Ravoo Bart Jan | Zendy

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Light‐Responsive Capture and Release of DNA in a Ternary Supramolecular Complex

Author(s) -

Nalluri Siva Krishna Mohan,

Voskuhl Jens,

Bultema Jelle B.,

Boekema Egbert J.,

Ravoo Bart Jan

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201103707

Subject(s) - ternary complex , supramolecular chemistry , ternary operation , dna , photoisomerization , computer science , chemistry , information retrieval , computational biology , biophysics , nanotechnology , crystallography , biology , biochemistry , materials science , programming language , enzyme , isomerization , crystal structure , catalysis

The wavelength determines whether DNA is captured in a light‐responsive ternary supramolecular complex or released (see scheme). The reversible binding of DNA is triggered by a photoisomerization, which switches the complex from a multivalent to a monovalent binding mode.

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