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Stoichiometric Reduction of CO 2 to CO by Aluminum‐Based Frustrated Lewis Pairs
Author(s) -
Ménard Gabriel,
Stephan Douglas W.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201103600
Subject(s) - frustration , atmosphere (unit) , stoichiometry , reduction (mathematics) , frustrated lewis pair , computer science , chemistry , lewis acids and bases , psychology , physics , mathematics , thermodynamics , catalysis , social psychology , organic chemistry , geometry
Reducing frustration : The reaction of Mes 3 P(CO 2 )(AlI 3 ) 2 in the presence of a CO 2 atmosphere results in the formation of Mes 3 P(CO 2 )(O(AlI 2 ) 2 )(AlI 3 ) and [Mes 3 PI][AlI 4 ] (Mes=2,4,6‐Me 3 C 6 H 2 ) with the evolution of CO.