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Solid‐State Redox Solutions: Microfabrication and Electrochemistry
Author(s) -
Yang Dezhi,
Han Lianhuan,
Yang Yang,
Zhao LiuBin,
Zong Cheng,
Huang YiFan,
Zhan Dongping,
Tian ZhongQun
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201103386
Subject(s) - microfabrication , materials science , nanotechnology , miniaturization , electrochemistry , microfluidics , microelectromechanical systems , electrode , chemistry , medicine , alternative medicine , pathology , fabrication
On solid ground : Mix‐valent iron hexacyanides (Fe III , Fe II , and Prussian blue) can replace NaCl crystal lattice units to form a solid‐state solution. A scanning electrochemical microcapillary (SECM) technique has been developed for the controllable microfabrication of the microcrystals. In situ confocal Raman spectra can also be obtained without exposure to any liquid environment. WE=working electrode, RE/CE=reference/counter electrode.