Oxygen Insertion Catalysis by sp 2  Carbon | Zendy

Frank Benjamin | Zendy; Blume Raoul | Zendy; Rinaldi Ali | Zendy; Trunschke Annette | Zendy; Schlögl Robert | Zendy

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Oxygen Insertion Catalysis by sp 2 Carbon

Author(s) -

Frank Benjamin,

Blume Raoul,

Rinaldi Ali,

Trunschke Annette,

Schlögl Robert

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201103340

Subject(s) - oxygen , catalysis , carbon fibers , chemistry , radiochemistry , materials science , organic chemistry , composite number , composite material

Black matter in catalysis : Graphitic carbon catalyzes the insertion of O atoms into acrolein. Such complex multistep atom rearrangements were believed to be the exclusive domain of metal (oxide) catalysis. In the C‐catalyzed process, the nucleophilic O atoms terminating the graphite (0001) surface abstract the formyl H atom and the activated aldehyde is oxidized by a mobile epoxide O atom. Thus, the sp 2 carbon acts as a bifunctional catalyst.

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