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A Multiferroic Perdeutero Metal–Organic Framework
Author(s) -
Fu DaWei,
Zhang Wen,
Cai HongLing,
Zhang Yi,
Ge JiaZhen,
Xiong RenGen,
Huang Songping D.,
Nakamura Takayoshi
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201103265
Subject(s) - multiferroics , dielectric , hysteresis , metal , coupling (piping) , materials science , metal organic framework , phase (matter) , condensed matter physics , nanotechnology , chemistry , nuclear magnetic resonance , ferroelectricity , physics , organic chemistry , optoelectronics , adsorption , metallurgy
Vitamin “D” : The perdeutero metal–organic framework [(CD 3 ) 2 ND 2 ][Co(DCOO) 3 ] (see structure) undergoes two phase transitions, including one above room temperature, which is unprecedented for metal formates. Magnetic and dielectric hysteresis loops make it an example of a multiferroic MOF without coupling of magnetic and electric ordering.