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Deconstruction of Capsules Using Chiral Spacers
Author(s) -
Yamauchi Yoshihiro,
Ajami Dariush,
Lee JiYeon,
Rebek Julius
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201103031
Subject(s) - deconstruction (building) , chemistry , host (biology) , scheme (mathematics) , chirality (physics) , stereochemistry , mathematics , physics , chiral symmetry , biology , ecology , quantum mechanics , nambu–jona lasinio model , quark , mathematical analysis
Interconvertible host : Extended cavitands and capsules that recognize n ‐alkanes were generated using N ‐methyl glycoluril as a chiral spacer. The two host assemblies were interconverted by factors such as temperature, concentration, and guest length (see scheme).