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Confinement of Mobile Histamine in Coordination Nanochannels for Fast Proton Transfer
Author(s) -
Umeyama Daiki,
Horike Satoshi,
Inukai Munehiro,
Hijikata Yuh,
Kitagawa Susumu
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102997
Subject(s) - histamine , anhydrous , microporous material , proton , chemistry , nanotechnology , physics , computer science , materials science , medicine , quantum mechanics , organic chemistry
Along narrow channels : Mutual integration of a microporous coordination polymer and histamine provides a proton conductivity above 10 −3 S cm −1 under anhydrous conditions. Anisotropic alignment of histamine molecules in straight 1D channels creates a specific conduction pathway (see picture).