Taking the Aromaticity out of Aromatic Interactions | Zendy

Bloom Jacob W. G. | Zendy; Wheeler Steven E. | Zendy

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Taking the Aromaticity out of Aromatic Interactions

Author(s) -

Bloom Jacob W. G.,

Wheeler Steven E.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102982

Subject(s) - aromaticity , delocalized electron , stacking , phrase , supramolecular chemistry , computer science , electron delocalization , non covalent interactions , chemistry , information retrieval , organic chemistry , natural language processing , crystal structure , molecule , hydrogen bond

What's in a name? The phrase “aromatic interactions” is widely used to describe noncovalent interactions involving aromatic rings. However, computed stacking energies suggest that disruption of the aromatic π delocalization can enhance many of these interactions and also render them orientation‐dependent. Because of these effects, the use of nonaromatic systems should be advantageous in supramolecular chemistry.

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