X‐ray Photolysis To Release Ligands from Caged Reagents by an Intramolecular Antenna Sensitive to Magnetic Resonance Imaging | Zendy

Petit Morgane | Zendy; Bort Guillaume | Zendy; Doan BichThuy | Zendy; Sicard Cécile | Zendy; Ogden David | Zendy; Scherman Daniel | Zendy; Ferroud Clotilde | Zendy; Dalko Peter I. | Zendy

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X‐ray Photolysis To Release Ligands from Caged Reagents by an Intramolecular Antenna Sensitive to Magnetic Resonance Imaging

Author(s) -

Petit Morgane,

Bort Guillaume,

Doan BichThuy,

Sicard Cécile,

Ogden David,

Scherman Daniel,

Ferroud Clotilde,

Dalko Peter I.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102948

Subject(s) - photodissociation , intramolecular force , irradiation , photochemistry , excitation , antenna (radio) , chemistry , reagent , magnetic resonance imaging , metal , x ray , electron transfer , materials science , nuclear magnetic resonance , optics , stereochemistry , physics , organic chemistry , computer science , medicine , telecommunications , quantum mechanics , nuclear physics , radiology

Sensitive to light : A metal‐complex‐sensitized organic probe was developed to release ligands on excitation by X‐ray or γ irradiation (see picture). This overcomes a current limitation in permitting use of photolysis as an experimental tool in otherwise inaccessible materials that are not penetrated by light (ET=electron transfer).

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