A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes | Zendy

Nakamula Ikuse | Zendy; Yamanoi Yoshinori | Zendy; Imaoka Takane | Zendy; Yamamoto Kimihisa | Zendy; Nishihara Hiroshi | Zendy

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A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes

Author(s) -

Nakamula Ikuse,

Yamanoi Yoshinori,

Imaoka Takane,

Yamamoto Kimihisa,

Nishihara Hiroshi

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102836

Subject(s) - bimetallic strip , dendrimer , rhodium , catalysis , nanoparticle , chemistry , catalytic hydrogenation , organic chemistry , materials science , polymer chemistry , nanotechnology

Mix and more than match : Relative to the catalytic activity of pure Rh nanoparticles in a dendrimer cage, Rh/Fe bimetallic nanoparticles in dendrimers have improved catalytic activity towards the hydrogenation of olefins, and unlike Wilkinson catalyst could catalyze nitroarene hydrogenation (see scheme, G4=4th generation dendrimer).

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