Square‐Planar Iridium(II) and Iridium(III) Amido Complexes Stabilized by a PNP Pincer Ligand | Zendy

Meiners Jenni | Zendy; Scheibel Markus G. | Zendy; LeméeCailleau MarieHélène | Zendy; Mason Sax A. | Zendy; Boeddinghaus M. Bele | Zendy; Fässler Thomas F. | Zendy; Herdtweck Eberhardt | Zendy; Khusniyarov Marat M. | Zendy; Schneider Sven | Zendy

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Square‐Planar Iridium(II) and Iridium(III) Amido Complexes Stabilized by a PNP Pincer Ligand

Author(s) -

Meiners Jenni,

Scheibel Markus G.,

LeméeCailleau MarieHélène,

Mason Sax A.,

Boeddinghaus M. Bele,

Fässler Thomas F.,

Herdtweck Eberhardt,

Khusniyarov Marat M.,

Schneider Sven

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102795

Subject(s) - iridium , pincer movement , pincer ligand , ligand (biochemistry) , square (algebra) , chemistry , crystallography , stereochemistry , mathematics , organic chemistry , catalysis , biochemistry , receptor , geometry

Squaring the circle : The novel dienamido pincer ligand N(CHCHP t Bu 2 ) 2 − affords the isolation of the unusual square‐planar iridium(II) and iridium(III) amido complexes [IrCl{N(CHCHP t Bu 2 ) 2 }] n ( n =0 ( 1 ), +1 ( 2 )). In contrast, the corresponding iridium(I) complex of the redox series ( n =−1) is surprisingly unstable. The diamagnetism of 2 is attributed to strong N→Ir π donation.

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