Assembly of the First Fullerene‐Type Metal–Organic Frameworks Using a Planar Five‐Fold Coordination Node | Zendy

Bacsa John | Zendy; Less Robert J. | Zendy; Skelton Helen E. | Zendy; Soracevic Zlatko | Zendy; Steiner Alexander | Zendy; Wilson Thomas C. | Zendy; Wood Paul T. | Zendy; Wright Dominic S. | Zendy

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Assembly of the First Fullerene‐Type Metal–Organic Frameworks Using a Planar Five‐Fold Coordination Node

Author(s) -

Bacsa John,

Less Robert J.,

Skelton Helen E.,

Soracevic Zlatko,

Steiner Alexander,

Wilson Thomas C.,

Wood Paul T.,

Wright Dominic S.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102783

Subject(s) - clathrate hydrate , planar , fullerene , fold (higher order function) , crystallization , sodium , molecule , metal organic framework , metal , crystallography , materials science , solvent , chemistry , hydrate , computer science , organic chemistry , adsorption , computer graphics (images) , programming language

Pump up the volume : Slow crystallization of Na[C 5 (CN) 5 ], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in which around 66 % of the unit cell volume is occupied by solvent molecules.

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