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Mixed‐Metal Lanthanide–Iron Triple‐Decker Complexes with a cyclo ‐P 5 Building Block
Author(s) -
Li Tianshu,
Wiecko Jelena,
Pushkarevsky Nikolay A.,
Gamer Michael T.,
Köppe Ralf,
Konchenko Sergey N.,
Scheer Manfred,
Roesky Peter W.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102748
Subject(s) - lanthanide , block (permutation group theory) , metal , samarium , monomer , dimer , chemistry , combinatorics , materials science , crystallography , inorganic chemistry , mathematics , organic chemistry , ion , polymer
Triple‐decker complexes with mixed d/f‐block metals that have a purely inorganic middle deck were unknown. A mixed‐metal iron–samarium complex is presented with a cyclo ‐P 5 polyphosphide between the metal centers (see picture; Sm large black, C small black, Fe blue, N green, O red, P pink). This compound can be obtained as either a monomer or a dimer depending on the reaction conditions.