Mixed‐Metal Lanthanide–Iron Triple‐Decker Complexes with a  cyclo ‐P 5  Building Block | Zendy

Li Tianshu | Zendy; Wiecko Jelena | Zendy; Pushkarevsky Nikolay A. | Zendy; Gamer Michael T. | Zendy; Köppe Ralf | Zendy; Konchenko Sergey N. | Zendy; Scheer Manfred | Zendy; Roesky Peter W. | Zendy

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Mixed‐Metal Lanthanide–Iron Triple‐Decker Complexes with a cyclo ‐P 5 Building Block

Author(s) -

Li Tianshu,

Wiecko Jelena,

Pushkarevsky Nikolay A.,

Gamer Michael T.,

Köppe Ralf,

Konchenko Sergey N.,

Scheer Manfred,

Roesky Peter W.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102748

Subject(s) - lanthanide , block (permutation group theory) , metal , samarium , monomer , dimer , chemistry , combinatorics , materials science , crystallography , inorganic chemistry , mathematics , organic chemistry , ion , polymer

Triple‐decker complexes with mixed d/f‐block metals that have a purely inorganic middle deck were unknown. A mixed‐metal iron–samarium complex is presented with a cyclo ‐P 5 polyphosphide between the metal centers (see picture; Sm large black, C small black, Fe blue, N green, O red, P pink). This compound can be obtained as either a monomer or a dimer depending on the reaction conditions.

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