Synthesis and Structural Characterization of Crystalline Nonacenes | Zendy

Purushothaman Balaji | Zendy; Bruzek Matthew | Zendy; Parkin Sean R. | Zendy; Miller AnneFrances | Zendy; Anthony John E. | Zendy

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Synthesis and Structural Characterization of Crystalline Nonacenes

Author(s) -

Purushothaman Balaji,

Bruzek Matthew,

Parkin Sean R.,

Miller AnneFrances,

Anthony John E.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201102671

Subject(s) - characterization (materials science) , electrochemistry , information retrieval , line (geometry) , computer science , content (measure theory) , surface modification , nanotechnology , chemistry , combinatorial chemistry , materials science , mathematics , mathematical analysis , geometry , electrode

Nine in a line : A multifaceted approach, including a silylethylene functionalization strategy, to the synthesis of stable nonacene derivatives (see picture, F green, Si blue) allows an unprecedented level of characterization, including electrochemical, photophysical, and crystallographic studies. The nonacenes show a strong S 0 –S 1 transition and no fluorescence in the visible region.

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