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Powerful Insight into Catalytic Mechanisms through Simultaneous Monitoring of Reactants, Products, and Intermediates
Author(s) -
Vikse Krista L.,
Ahmadi Zohrab,
Manning Cara C.,
Harrington David A.,
McIndoe J. Scott
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102630
Subject(s) - phenylacetylene , catalysis , aryl , iodide , chemistry , mass spectrometry , electrospray ionization , palladium , combinatorial chemistry , computer science , database , organic chemistry , chromatography , alkyl
Keeping an eye on all the players : The combination of bulky phosphonium tags and pressurized sample infusion transforms electrospray ionization mass spectrometry into a tool capable of producing dense data on the relative concentrations of all components of a catalytic reaction, such as the palladium‐catalyzed coupling of an aryl iodide with phenylacetylene (see graph).