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Cover Picture: Redox‐Controlled Magnetic {Mn 13 } Keggin Systems (Angew. Chem. Int. Ed. 25/2011)
Author(s) -
Newton Graham N.,
Yamashita Satoshi,
Hasumi Koen,
Matsuno Junzo,
Yoshida Norifumi,
Nihei Masayuki,
Shiga Takuya,
Nakano Motohiro,
Nojiri Hiroyuki,
Wernsdorfer Wolfgang,
Oshio Hiroki
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102590
Subject(s) - redox , nanoclusters , cover (algebra) , manganese oxide , manganese , materials science , oxide , crystallography , chemistry , nanotechnology , inorganic chemistry , organic chemistry , mechanical engineering , engineering
Manganese oxide nanoclusters with α‐Keggin‐type cores and redox‐tunable magnetic behavior were synthesized by H. Oshio et al. In their Communication on page 5716 ff., they report that the clusters could be oxidized in one‐electron steps, leading to increases in the single‐molecule‐magnetic properties. The image shows the transition from a {Mn 13 } 4+ species through {Mn 13 } 5+ to {Mn 13 } 6+ and the changes in the resultant hysteretic responses.