Premium
The Halogen Bond and Internal Dynamics in the Molecular Complex of CF 3 Cl and H 2 O
Author(s) -
Evangelisti Luca,
Feng Gang,
Écija Patricia,
Cocinero Emilio J.,
Castaño Fernando,
Caminati Walther
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102544
Subject(s) - isotopologue , halogen , monomer , fourier transform , halogen bond , crystallography , set (abstract data type) , chemistry , molecule , physics , computer science , organic chemistry , quantum mechanics , alkyl , polymer , programming language
Molecular spinning tops : Five halogen‐bonded isotopologues of the CF 3 Cl–H 2 O complex have been assigned by Fourier‐transform microwave spectroscopy. All complexes are symmetric‐top systems with evenly spaced bonds. The free internal rotation, relative stability, and structure of these complexes were determined (see picture; Ψ, θ , and Φ : angles, a and b : axes of the monomer, and A : axis of the complex).