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Synthesis of Undecachlorosulfolipid A: Re‐evaluation of the Nominal Structure
Author(s) -
Nilewski Christian,
Deprez Nicholas R.,
Fessard Thomas C.,
Li Dong Bo,
Geisser Roger W.,
Carreira Erick M.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102521
Subject(s) - scheme (mathematics) , computer science , halo , information retrieval , product (mathematics) , natural (archaeology) , world wide web , mathematics , history , physics , astrophysics , mathematical analysis , geometry , galaxy , archaeology
Halo‐giant : The title compound at the left in the scheme was constructed by the synthesis and coupling of two stereochemically challenging fragments. A comparison of the NMR data of the synthetic material and the natural product indicates that the configuration had been misassigned in the latter. PT=5‐(1‐phenyltetrazolyl).