Premium
Molecular Lanthanoid–Transition‐Metal Cluster through CH Bond Activation by Polar Metal–Metal Bonds
Author(s) -
Butovskii Mikhail V.,
Tok Oleg L.,
Bezugly Viktor,
Wagner Frank R.,
Kempe Rhett
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102363
Subject(s) - metal , lanthanide , chemistry , transition metal , ligand (biochemistry) , crystallography , moiety , cluster (spacecraft) , stereochemistry , organic chemistry , catalysis , ion , biochemistry , receptor , computer science , programming language
Cp glue : A chiral four‐coordinate organolanthanoid complex, which has an unsupported metal–metal bond, reacts to give a lanthanoid–transition‐metal cluster with two‐electron multicenter metal–metal bonds (see structure). The reaction proceeds through CH bond activation by the polar metal–metal bonds and affords a 1,2‐dimetallation of one Cp ligand of the metallocene moiety.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom