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Molecular Lanthanoid–Transition‐Metal Cluster through CH Bond Activation by Polar Metal–Metal Bonds
Author(s) -
Butovskii Mikhail V.,
Tok Oleg L.,
Bezugly Viktor,
Wagner Frank R.,
Kempe Rhett
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102363
Subject(s) - metal , lanthanide , chemistry , transition metal , ligand (biochemistry) , crystallography , moiety , cluster (spacecraft) , stereochemistry , organic chemistry , catalysis , ion , biochemistry , receptor , computer science , programming language
Cp glue : A chiral four‐coordinate organolanthanoid complex, which has an unsupported metal–metal bond, reacts to give a lanthanoid–transition‐metal cluster with two‐electron multicenter metal–metal bonds (see structure). The reaction proceeds through CH bond activation by the polar metal–metal bonds and affords a 1,2‐dimetallation of one Cp ligand of the metallocene moiety.