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Efficient Sunlight‐Driven Dehydrogenative Coupling of Methane to Ethane over a Zn + ‐Modified Zeolite
Author(s) -
Li Lu,
Li GuoDong,
Yan Chang,
Mu XiaoYue,
Pan XiaoLiang,
Zou XiaoXin,
Wang KaiXue,
Chen JieSheng
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102320
Subject(s) - zeolite , methane , catalysis , sunlight , photochemistry , zinc , irradiation , chemistry , photocatalysis , organic chemistry , physics , optics , nuclear physics
Sun bath : A Zn + ‐modified zeolite catalyst showing superior photocatalytic activity for the activation of a CH bond converted methane into ethane and hydrogen upon irradiation of sunlight (see picture). Light at wavelengths shorter than 390 nm transferred electrons from the zeolite framework to the zinc centers.
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