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Reactivity of a Scandium Terminal Imido Complex Towards Unsaturated Substrates
Author(s) -
Chu Jiaxiang,
Lu Erli,
Liu Zhixiao,
Chen Yaofeng,
Leng Xuebing,
Song Haibin
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201102267
Subject(s) - scandium , cyclopentadiene , reactivity (psychology) , methyl methacrylate , propylene oxide , chemistry , terminal (telecommunication) , polymer chemistry , organic chemistry , polymer , catalysis , polymerization , copolymer , computer science , medicine , telecommunications , alternative medicine , ethylene oxide , pathology
A complex complex : The reactions of a scandium terminal imido complex with a series of unsaturated substrates, including CO 2 , PhCN, methyl methacrylate (MMA), cyclopentadiene, PhNCO, and propylene oxide, are presented (see scheme). A variety of intriguing products are formed from this complex. Ar=2,6‐( i Pr) 2 C 6 H 3 .