CO 2 ‐“Neutral” Hydrogen Storage Based on Bicarbonates and Formates | Zendy

Boddien Albert | Zendy; Gärtner Felix | Zendy; Federsel Christopher | Zendy; Sponholz Peter | Zendy; Mellmann Dörthe | Zendy; Jackstell Ralf | Zendy; Junge Henrik | Zendy; Beller Matthias | Zendy

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CO 2 ‐“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

Author(s) -

Boddien Albert,

Gärtner Felix,

Federsel Christopher,

Sponholz Peter,

Mellmann Dörthe,

Jackstell Ralf,

Junge Henrik,

Beller Matthias

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101995

Subject(s) - dehydrogenation , hydrogen storage , ruthenium , hydrogen , catalysis , methane , chemistry , inorganic chemistry , base (topology) , organic chemistry , mathematical analysis , mathematics

Let the circle be unbroken! One ruthenium catalyst generated in situ facilitates the selective hydrogenation of bicarbonates and carbonates, as well as CO 2 and base, to give formates and also the selective dehydrogenation of formates back to bicarbonates. The two reactions can be coupled, leading to a reversible hydrogen‐storage system. dppm=1,2‐bis(diphenylphosphino)methane.

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