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Catalytic Oxidation of Silanes by Carbon Nanotube–Gold Nanohybrids
Author(s) -
John Jubi,
Gravel Edmond,
Hagège Agnès,
Li Haiyan,
Gacoin Thierry,
Doris Eric
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101993
Subject(s) - silanes , silane , catalysis , alkyl , nanotube , aryl , carbon nanotube , chemistry , nanotechnology , materials science , organic chemistry , combinatorial chemistry
Turning over silanes : The first nanotube‐based catalytic system for silane oxidation is reported (see scheme). The reusable gold–nanotube hybrid cleanly oxidizes both alkyl and aryl silanes in high yields, under mild reaction conditions, and compares most favorably to any other catalytic system in terms of overall efficacy and turnover values.