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Tetrahedral Mo 4 Clusters as Building Blocks for the Design of Clathrate‐Related Giant Frameworks
Author(s) -
Shestopalov Michael A.,
Ledneva Alexandra Y.,
Cordier Stéphane,
Hernandez Olivier,
Potel Michel,
Roisnel Thierry,
Naumov Nikolai G.,
Perrin Christiane
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101986
Subject(s) - clathrate hydrate , delocalized electron , cluster (spacecraft) , tetrahedron , atom (system on chip) , crystallography , materials science , chemical physics , chemistry , nanotechnology , hydrate , computer science , programming language , organic chemistry , embedded system
Cluster‐based clathrate : Mo 4 S i 4 Cl a 12 inorganic building blocks (see picture, i=inner, a=apical) containing Mo 4 metal atom clusters assemble to yield an inorganic giant framework structurally related to type II clathrate. This compound is the first member of a promising family of materials with a wide range of physical properties that combine the chemistry of metallic clusters characterized by delocalized electrons with that of inorganic clathrates.

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