Palladium‐Catalyzed Elimination/Isomerization of Enol Triflates into 1,3‐Dienes | Zendy

Crouch Ian T. | Zendy; Dreier Timothy | Zendy; Frantz Doug E. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Palladium‐Catalyzed Elimination/Isomerization of Enol Triflates into 1,3‐Dienes

Author(s) -

Crouch Ian T.,

Dreier Timothy,

Frantz Doug E.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101820

Subject(s) - isomerization , allene , palladium , enol , chemistry , cationic polymerization , catalysis , hydride , medicinal chemistry , photochemistry , organic chemistry , hydrogen

Dying to be Dienes: Substituted 1,3‐dienes were synthesized by the title reaction (see scheme; Tf=trifluoromethanesulfonyl). Preliminary studies support a mechanistically distinct pathway that involves an initial β‐hydride elimination from a cationic vinyl palladium(II) intermediate, a subsequent regiospecific hydropalladation of the corresponding allene intermediate, and a final β‐hydride elimination.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research