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High and Highly Anisotropic Proton Conductivity in Organic Molecular Porous Materials
Author(s) -
Yoon Minyoung,
Suh Kyungwon,
Kim Hyunuk,
Kim Yonghwi,
Selvapalam Narayanan,
Kim Kimoon
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101777
Subject(s) - isostructural , conductivity , materials science , proton , porosity , anisotropy , porous medium , molecule , thermal conduction , cucurbituril , chemical engineering , chemical physics , supramolecular chemistry , crystal structure , chemistry , crystallography , composite material , organic chemistry , optics , physics , quantum mechanics , engineering
Cucurbituril‐based organic molecular porous materials with 1D channels filled with water–acid arrays were synthesized. The isostructural materials showed different proton conductivity depending on the nature and number of acid molecules present in the channels. The highly anisotropic conduction behavior of the materials was studied by single‐crystal conductivity measurements.