Highly Conducting Coordination Polymers Based on Infinite M(4,4′‐bpy) Chains Flanked by Regular Stacks of Non‐Integer TCNQ Radicals | Zendy

BallesterosRivas Maria | Zendy; Ota Akira | Zendy; Reinheimer Eric | Zendy; Prosvirin Andrey | Zendy; ValdésMartinez Jesús | Zendy; Dunbar Kim R. | Zendy

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Highly Conducting Coordination Polymers Based on Infinite M(4,4′‐bpy) Chains Flanked by Regular Stacks of Non‐Integer TCNQ Radicals

Author(s) -

BallesterosRivas Maria,

Ota Akira,

Reinheimer Eric,

Prosvirin Andrey,

ValdésMartinez Jesús,

Dunbar Kim R.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101658

Subject(s) - tetracyanoquinodimethane , radical , block (permutation group theory) , type (biology) , polymer , integer (computer science) , crystallography , chemistry , materials science , computer science , combinatorics , mathematics , molecule , organic chemistry , ecology , biology , programming language

All coordinated : Highly conducting coordination polymers of the type [M(4,4′‐bpy)(η 1 ‐TCNQ) 2 (CH 3 OH) 2 ]TCNQ (M=Mn, Zn) have been realized by using TCNQ (7,7,8,8‐tetracyanoquinodimethane) as a building block (see picture). Regularly spaced stacks of TCNQ are connected to a Mn II –4,4′‐bipyridine spine by two η 1 ‐TCNQ ligands involved in a stacked column with free TCNQ radicals.

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