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Highly Conducting Coordination Polymers Based on Infinite M(4,4′‐bpy) Chains Flanked by Regular Stacks of Non‐Integer TCNQ Radicals
Author(s) -
BallesterosRivas Maria,
Ota Akira,
Reinheimer Eric,
Prosvirin Andrey,
ValdésMartinez Jesús,
Dunbar Kim R.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101658
Subject(s) - tetracyanoquinodimethane , radical , block (permutation group theory) , type (biology) , polymer , integer (computer science) , crystallography , chemistry , materials science , computer science , combinatorics , mathematics , molecule , organic chemistry , ecology , biology , programming language
All coordinated : Highly conducting coordination polymers of the type [M(4,4′‐bpy)(η 1 ‐TCNQ) 2 (CH 3 OH) 2 ]TCNQ (M=Mn, Zn) have been realized by using TCNQ (7,7,8,8‐tetracyanoquinodimethane) as a building block (see picture). Regularly spaced stacks of TCNQ are connected to a Mn II –4,4′‐bipyridine spine by two η 1 ‐TCNQ ligands involved in a stacked column with free TCNQ radicals.