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Simple, Stable, and Easily Accessible Well‐Defined CuCF 3 Aromatic Trifluoromethylating Agents
Author(s) -
Tomashenko Olesya A.,
EscuderoAdán Eduardo C.,
Martínez Belmonte Marta,
Grushin Vladimir V.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101577
Subject(s) - simple (philosophy) , yield (engineering) , computer science , scheme (mathematics) , content (measure theory) , state (computer science) , combinatorial chemistry , information retrieval , chemistry , mathematics , programming language , philosophy , epistemology , physics , thermodynamics , mathematical analysis
Give me an F : Exceptionally easy to make in over 90 % yield (see scheme) and air‐stable in the solid state, [(Ph 3 P) 3 Cu(CF 3 )] is a remarkable example of a rarely encountered well‐defined Cu(I) trifluoromethylating agent and a convenient starting material for the synthesis of other CuCF 3 complexes, such as [(phen)Cu(PPh 3 )(CF 3 )].