Crystallographic Realization of the Mathematically Predicted Densest All‐Pentagon Packing Lattice by  C  5 ‐Symmetric “Sticky” Fluoropentamers | Zendy

Ren Changliang | Zendy; Zhou Feng | Zendy; Qin Bo | Zendy; Ye Ruijuan | Zendy; Shen Sheng | Zendy; Su Haibin | Zendy; Zeng Huaqiang | Zendy

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Crystallographic Realization of the Mathematically Predicted Densest All‐Pentagon Packing Lattice by C 5 ‐Symmetric “Sticky” Fluoropentamers

Author(s) -

Ren Changliang,

Zhou Feng,

Qin Bo,

Ye Ruijuan,

Shen Sheng,

Su Haibin,

Zeng Huaqiang

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101553

Subject(s) - pentagon , intermolecular force , lattice (music) , crystallography , realization (probability) , crystal structure , sphere packing , combinatorics , molecule , computer science , materials science , chemistry , mathematics , physics , geometry , organic chemistry , statistics , acoustics

Regular pentagonal adhesive tiles were obtained by designing a cyclic fluoropentamer with an internal CF ⋅⋅⋅ HN H‐bonded network and “sticky” edges that can glue the molecules together through intermolecular C Ar H ⋅⋅⋅ OC H bonds. In the crystal they form the mathematically predicted densest all‐pentagon 2D lattice with a packing density of 0.921 (see picture).

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