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Facile Conversion of CO/H 2 into Methoxide at a Uranium(III) Center
Author(s) -
Frey Alistair S. P.,
Cloke F. Geoffrey N.,
Coles Martyn P.,
Maron Laurent,
Davin Thomas
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101509
Subject(s) - methoxide , toluene , uranium , center (category theory) , chemistry , computer science , database , combinatorial chemistry , organic chemistry , catalysis , physics , crystallography , nuclear physics
Hydrogenation of CO : The reaction of [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)] in toluene with CO and H 2 at subambient to ambient temperature and pressure affords the methoxide complex [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)OMe].