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Mutual Activation: Suzuki–Miyaura Coupling through Direct Cleavage of the sp 2 CO Bond of Naphtholate
Author(s) -
Yu DaGang,
Shi ZhangJie
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101461
Subject(s) - boronic acid , aryl , cleavage (geology) , catalysis , chemistry , bond cleavage , combinatorial chemistry , ring (chemistry) , stereochemistry , organic chemistry , materials science , fracture (geology) , alkyl , composite material
Working together : A new approach of mutual activation between naphtholates and aryl boronic acid derivatives by the formation of borates to facilitate the Suzuki–Miyaura coupling through direct cleavage of the sp 2 CO bond by nickel catalysis is described (see scheme; R′: annulated ring system). Various naphtholates and aryl boronic acid derivatives could be directly coupled in good yields.