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Base‐Driven Assembly of Large Uranium Oxo/Hydroxo Clusters
Author(s) -
Biswas Biplab,
Mougel Victor,
Pécaut Jacques,
Mazzanti Marinella
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101327
Subject(s) - uranium , cluster (spacecraft) , computer science , base (topology) , stoichiometry , aqueous solution , process (computing) , hydrolysis , chemistry , combinatorial chemistry , information retrieval , physics , organic chemistry , programming language , nuclear physics , mathematics , mathematical analysis
Uranium building blocks : Two new uranium cluster topologies are obtained from the stoichiometric hydrolysis of low‐valent uranium in non‐aqueous media (see picture). The organic base TMEDA directs the self‐assembly process towards the formation of a nanosized oxo‐hydroxo U 16 cluster.