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Dimerization of a Metal Complex through Thermally Induced Single‐Crystal‐to‐Single‐Crystal Transformation or Mechanochemical Reaction
Author(s) -
Sun Jie,
Dai Fangna,
Yuan Wenbing,
Bi Wenhua,
Zhao Xiaoliang,
Sun Wenming,
Sun Daofeng
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101277
Subject(s) - carboxylate , copper , single crystal , crystallography , metal , transformation (genetics) , crystal structure , monomer , chemistry , crystal (programming language) , materials science , photochemistry , stereochemistry , polymer , organic chemistry , biochemistry , computer science , programming language , gene
Come together : Monomers of copper carboxylate complex 1 (see picture, Cu blue‐green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H‐bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single‐crystal‐to‐single‐crystal transformation or by mechanochemical reaction.