Dimerization of a Metal Complex through Thermally Induced Single‐Crystal‐to‐Single‐Crystal Transformation or Mechanochemical Reaction | Zendy

Sun Jie | Zendy; Dai Fangna | Zendy; Yuan Wenbing | Zendy; Bi Wenhua | Zendy; Zhao Xiaoliang | Zendy; Sun Wenming | Zendy; Sun Daofeng | Zendy

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Dimerization of a Metal Complex through Thermally Induced Single‐Crystal‐to‐Single‐Crystal Transformation or Mechanochemical Reaction

Author(s) -

Sun Jie,

Dai Fangna,

Yuan Wenbing,

Bi Wenhua,

Zhao Xiaoliang,

Sun Wenming,

Sun Daofeng

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101277

Subject(s) - carboxylate , copper , single crystal , crystallography , metal , transformation (genetics) , crystal structure , monomer , chemistry , crystal (programming language) , materials science , photochemistry , stereochemistry , polymer , organic chemistry , biochemistry , computer science , programming language , gene

Come together : Monomers of copper carboxylate complex 1 (see picture, Cu blue‐green, N blue, O red, S yellow, C gray) can dimerize to 2 when previously H‐bonded carboxylate groups coordinate to copper. This dimerization can be induced by thermal single‐crystal‐to‐single‐crystal transformation or by mechanochemical reaction.

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