[Au(CF 3 )(CO)]: A Gold Carbonyl Compound Stabilized by a Trifluoromethyl Group | Zendy

MartínezSalvador Sonia | Zendy; Forniés Juan | Zendy; Martín Antonio | Zendy; Menjón Babil | Zendy

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[Au(CF 3 )(CO)]: A Gold Carbonyl Compound Stabilized by a Trifluoromethyl Group

Author(s) -

MartínezSalvador Sonia,

Forniés Juan,

Martín Antonio,

Menjón Babil

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101231

Subject(s) - trifluoromethyl , chemistry , molecule , trigonal crystal system , group (periodic table) , crystallography , stereochemistry , medicinal chemistry , crystal structure , organic chemistry , alkyl

Fluorination operates for good : A trifluoromethyl group is able to stabilize the title compound (see picture; Au yellow, C gray, F green, O red), which formed by low‐temperature treatment of [PPh 4 ][Au(CF 3 ) 2 ] with BF 3 ⋅OEt 2 . A trigonal environment is adopted by each molecule with aurophilic interactions with three near‐neighbors in a global triskelion arrangement.

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