Hydrogen Storage in Magnesium Hydride: The Molecular Approach | Zendy

Harder Sjoerd | Zendy; Spielmann Jan | Zendy; Intemann Julia | Zendy; Bandmann Heinz | Zendy

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Hydrogen Storage in Magnesium Hydride: The Molecular Approach

Author(s) -

Harder Sjoerd,

Spielmann Jan,

Intemann Julia,

Bandmann Heinz

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201101153

Subject(s) - hydrogen storage , hydride , magnesium hydride , cluster (spacecraft) , hydrogen , magnesium , desorption , hydrogen molecule , inorganic chemistry , ion , coupling (piping) , materials science , chemistry , crystallography , metallurgy , organic chemistry , computer science , adsorption , operating system

Big can be small : The largest ligand‐stabilized magnesium hydride cluster, containing 8 Mg 2+ and 10 H − ions, is a model for the smallest sub‐nanometer‐sized hydrogen storage material. This molecular cluster displays magnetic hydride–hydride coupling (see picture) and complete hydrogen desorption at the record‐low temperature of 200 °C.

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