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Reaction of Frustrated Lewis Pairs with Conjugated Ynones‐Selective Hydrogenation of the Carbon–Carbon Triple Bond
Author(s) -
Xu BaoHua,
Kehr Gerald,
Fröhlich Roland,
Wibbeling Birgit,
Schirmer Birgitta,
Grimme Stefan,
Erker Gerhard
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101051
Subject(s) - frustrated lewis pair , conjugated system , triple bond , carbon fibers , chemistry , reinforced carbon–carbon , lewis acids and bases , polymer chemistry , catalysis , organic chemistry , materials science , double bond , polymer , composite material , composite number
Frustrated, but not frustrating : Frustrated Lewis pairs (FLPs) can undergo selective 1,4‐addition reactions with conjugated ynones (see scheme). Upon FLP dihydrogen activation selective hydrogenation of the carbon–carbon triple bond can be achieved, in one case even catalytically.