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Synthesis of Anionic Iron Polyphosphides by Reaction of White Phosphorus with “Cp*Fe − ”
Author(s) -
Schnöckelborg EvaMaria,
Weigand Jan J.,
Wolf Robert
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201101038
Subject(s) - white phosphorus , phosphorus , chemistry , content (measure theory) , quantum chemical , nuclear magnetic resonance spectroscopy , database , crystallography , combinatorial chemistry , molecule , organic chemistry , computer science , mathematics , mathematical analysis
Transforming P 4 : The reaction of the anionic Cp*Fe − equivalent 1 with white phosphorus is a promising new approach toward P 4 activation. The reaction proceeded under mild conditions and enabled the synthesis of remarkable anionic polyphosphido complexes. Two new iron polyphosphides 2 and 3 were isolated and characterized by X‐ray crystallography, 31 P NMR spectroscopy, and quantum chemical calculations.